Six new macrocyclic complexes were synthesized by template reaction of (±) - 1, 4 - bis(3 - aminopropoxy)butane with metal(II) nitrate and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane or 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and their structures were proposed on the basis of elemental analysis, FT-IR, UV-Vis, molar conductivity measurements, ¹H NMR and mass spectra. The metals to ligand molar ratios of the complexes were found to be 1 : 1. The complexes are 1 : 2 electrolytes for Pb(II) and Zn(II) complexes and 1 : 3 electrolytes for La(III) as shown by their molar conductivities (_m) in DMSO at 10^–3 mol.L^–1. Due to the existence of free ions in these complexes, such complexes are electrically conductive. The configurations of La(III) and Zn(II) complexes were proposed to probably octahedral.

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