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Teplofizika vysokikh temperatur
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tom 45, № 3, Mai-Iyun' 2007, S. 347-354
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TERMODINAMIKA UZrFeO-RASPLAVOV V. G. Asmolov, V. N. Zagryazkin, D. F. Tsurikov RNTs “Kurchatovskii institut”, Moskva Postupila v redaktsiyu 18.05.2006 g.
Ob"em i dostovernost' eksperimental'nykh dannykh po termodinamicheskim svoistvam sistem UO, ZrO i UZrO, a takzhe po rastvorimosti kisloroda v rasplavlennykh urane i tsirkonii nedostatochny dlya postroeniya termodinamicheskoi modeli vzaimodeistviya rasplavlennogo koriuma so splavami na osnove Fe. V kachestve modeli rasplava mnogokomponentnogo koriuma, sostoyashchego iz metallov i metalloidov, predlozheno rassmatrivat' atomarnyi rastvor zameshcheniya, obladayushchii svoistvami regulyarnogo rastvora. Neobkhodimye dlya etogo parametry vzaimodeistviya atomov metallov s kislorodom opredelyayutsya iz analiza ravnovesiya oksidnogo i metallicheskogo rasplavov v eksperimentakh serii STFM-Fe. Sformulirovannaya v rezul'tate model' pozvolyaet sdelat' prognoznye otsenki vzaimodeistviya rasplava UZrO-koriuma s zhelezom.
PACS: 28.41.Te, 67.55.Cx
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PII: S0040364407030040
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